31CrMoV9 | DIN 1.8519 Nitriding Steel in Stock

31CrMoV9 is a high-hardenability alloy nitriding structural steel according to the European standard EN10085. The numbers and element symbols in its name indicate its main components: approximately 0.31% carbon, approximately 2.25% chromium, and it also contains molybdenum and vanadium.

31CrMoV9 steel, with its high strength, high toughness, excellent high-temperature stability, and outstanding nitriding performance, occupies an important position in the high-end equipment manufacturing industry. Its unique alloy element ratio (Cr-Mo-V) makes it perform exceptionally well in high-temperature, high-fatigue, and high-wear environments, making it particularly suitable for precision parts requiring surface nitriding treatment.

31CrMoV9 Forged round steel with annealed condition

31CrMoV9 Chemical Composition

GradeCSiMnPSCrMoV
31CrMoV9/1.85190.27-0.34≤0.4 0.40-0.70≤0.025≤0.0352.3-2.70.15-0.250.1-0.2

31CrMoV9 Physical Properties (20℃)

  • Density: 7.73 kg/dm³
  • Elastic Modulus: 210 GPa
  • Thermal Conductivity: 43.0 W/m·K
  • Resistivity: 0.19 Ω·mm²/m
  • Specific Heat Capacity: 441 J/kg·K
  • Critical Point: AC₁=775℃

31CrMoV9 Forging

  • Initial forging temperature: 1050-1150℃ (not exceeding 1180℃ to prevent coarse grains)
  • Final forging temperature: ≥850℃ (forging below 850℃ is strictly prohibited)
  • Forging ratio: ≥4:1 (to improve microstructure and enhance mechanical properties)
  • Post-Forging Treatment:For 31CrMoV9 steel, the recommended practice is to perform annealing heat treatment immediately after forging.

31CrMoV9 Steel Heat Treatment

31CrMoV9 Softening Annealing (Pretreatment)

  • Temperature: 680-720℃, hold for 2-4 hours
  • Cooling: Slow furnace cooling (≤50℃/h)
  • Purpose: To relieve internal stress, improve machinability, and reduce hardness to ≤248 HB

31CrMoV9 Quenching

  • Water Quenching: 840-870℃, suitable for small cross-section parts, deeper hardened layer, but higher risk of deformation and stress concentration.
  • Oil Quenching: 850-880℃, suitable for large cross-section parts (>100mm), lower quenching stress and more stable core properties, but slightly shallower hardened depth.

31CrMoV9 Tempering

Single-stage tempering: 540-680℃, hold for 2 hours, air cool.

Hardness vs. temperature:

  • 680℃ tempering: approx. 24 HRC, tensile strength approx. 1000 MPa
  • 620℃ tempering: approx. 28 HRC, tensile strength approx. 1050 MPa
  • 560℃ tempering: approx. 32 HRC, tensile strength approx. 1150 MPa

Multi-stage tempering: First, high temperature (650℃) to relieve stress, then low temperature (200℃) to increase surface hardness, suitable for precision molds.

31CrMoV9 Mechanical properties (quenched and tempered state)

Tensile,Mpa
Yield,Mpa
Elongation,%
Reduction,%
Charpy Impact,J Hardness,HB
1080-1275 MPa≥930 MPa≥10%≥45%≥25 270-310

31CrMoV9 Nitriding Treatment (Surface Strengthening)

  • Gas Nitriding: 480-570℃, holding time 16-100 hours
  • Surface Hardness: 750-1000 HV, wear resistance improved by 3-5 times
  • Deformation: Tooth profile deformation after vacuum nitriding is only 0.01-0.03mm, eliminating the need for gear grinding.

31CrMoV9 Application

IndustryTypical applications
Energy and PowerSteam turbine blades, generator shafts, high-temperature and high-pressure pipelines
PetrochemicalsReactors, pressure vessels, drill pipe joints
Automotive ManufacturingEngine crankshafts, connecting rods, gearbox gears
AerospaceEngine components, high-strength fasteners
Machinery ManufacturingHigh-precision gears, hydraulic piston rods, precision molds

31CrMoV9 Supply Form & Size

  • Round Bars:  Dia.80 – 1,000mm as Forged
  • Flat / Square Bars:  Thickness Max.800mm
  • Shafts, Rollers, Blocks:  Customized or According to Drawing
  • Rolled Round Bars:  Dia.20 – 90mm with UT Assurance in stock

Heat treatment: Normalizing (+N), Annealing (+A),Quenched & Tempered(QT)
Surface finish:Black / Rough turned / Peeled